| Alkyne‐based Nanostructures on Silver Substrates 2018 Edition Contributor(s): Hellwig, Raphael (Author) |
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ISBN: 3030009963 ISBN-13: 9783030009960 Publisher: Springer OUR PRICE: $104.49 Product Type: Hardcover Published: November 2018 |
| Additional Information |
| BISAC Categories: - Science | Nanoscience - Science | Chemistry - Organic - Technology & Engineering | Materials Science - Thin Films, Surfaces & Interfaces |
| Dewey: 547.05 |
| Series: Springer Theses |
| Physical Information: 0.38" H x 6.14" W x 9.21" (0.82 lbs) 119 pages |
| Descriptions, Reviews, Etc. |
| Publisher Description: Acetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the authors establish protocols to fabricate regular architectures built up by the on-surface formation of selective organometallic and C-C bonds with thoughtfully designed alkyne-functionalized monomers. The structural and functional properties of the resulting organometallic and covalent nanostructures are characterized by means of scanning tunneling microscopy. The results open up new perspectives in the fields of heterogeneous catalysis and the on-surface synthesis of functional interfaces under mild reaction conditions. |